Excitation energies, oscillator strengths, and lifetimes of
levels in B~I, Al~I, Ga~I, In~I, and Tl~I

U. I. Safronova

Physics Department 220, University of Nevada, Reno, NV 89557, USA

The energies of the ground np states and the lowest ns and nd states in neutral
B, Al, Ga, In and Tl are obtained by using relativistic many-body perturbation
theory (RMBPT) method. First-, second-, third-order, and 'all order' Coulomb
energies and first- and second-order Breit energies are calculated.
Transition matrix elements provide another test of quality of atomic-structure
calculations and another measure of the size of correlation corrections.
Reduced matrix elements of the dipole operator in first-, second-, third- and
'all order'- perturbation theory between low-lying states of B~I, Al~I, Ga~I,
In~I, and Tl~I are presented. Second-order matrix element are extended to include
all high-order correction associated with the random-phase approximation (RPA).
These second-order calculations are practically gauge independent. The third-order
matrix elements include (RPA) plus Bruekner-orbital, structural radiation, and normalization correction. Results for a limited number states are obtained in the relativistic single-double (SD) approximation, where single and double excitations of Dirac-Fock wave functions are included to 'all orders' in perturbation theory. Using SD wave functions, accurate values are obtained for energies of the lowest states and for the possible electric-dipole matrix elements between these states. With the aid of the SD wave functions, we also determine transition rates and oscillator strengths together with lifetimes levels. These calculations provide a theoretical benchmark for comparison with experiment and theory.


This work was supported by DOE-NNSA/NV Cooperative Agreement
DE-FC08-01NV14050.